Just installed MATE on my laptop running Ubuntu 16.04 and I tried to get to mate-screenshot the same behaviour as gnome-screenshot does in Unity: just press Shift+Print to choose the portion of the screen that you want to capture. The corresponding command to be executed under MATE should be "mate-screenshot -a", executing it manually works, but trying to set it as custom shortcut doesn't work, it does nothing.
Any ideas?
mate-screenshot -a
, which worked fine. Is there any possibility of hardware issues ? ( meaning, can you try another keyboard ?)