I cannot find the Start-up Applications in 14.04, I read on a forum that you had to go into Main Menu and allow it to be visible through preferences, but I have looked all the way through preferences and I still haven't found it????
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Easiest method is to search for "start" in dash:
It is also possible to start it from command line, the command is
gnome-session-propertiesanyway, or try searching for 'startup' in your native language.