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With older ubuntu changing languages with alt+shift was easy to enable but on 13.10 I can not do this task at all can any one help me ??

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Hello you can find this answer in the following link.

Askubuntu Alt Shift Combo

Seems the solution is simply adding space to the combination keys that you want to use for shortcuts.

The following link confirms the issue

https://bugs.launchpad.net/ubuntu/+source/indicator-keyboard/+bug/1218322

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