I have an almost default install of Gnome Documents 3.6.2 on Gnome Shell 3.6.2 on Ubuntu 13.04. When I open Gnome Documents, it opens the window with "New" and "Recent" documents showing. By clicking ...
So, I have just setup my custom domain through domains.live.com. I have the docs etc working, I can sign in at office.com and view/create/upload documents, and the account is setup in gnome-shells ...