From the X.Org Wiki:
You can enable TV-Out either dynamically (by issuing commands to the running X server) or statically (through the xorg.config file, before starting the X server). For testing, the dynamic method is probably easier.
Enabling TV-Out Dynamically
TV-out may be enabled by using a recent driver and xrandr utility:
xrandr --addmode S-video 800x600
xrandr --output S-video --mode 800x600
xrandr --output S-video --set tv_standard ntsc
Enabling TV-Out Statically
Several options need to be specified. See the radeon(4) manpage for a description. In particular, you must set "TVStandard" to match your flavour of video.
This recipe is not definitive, but it has worked.
In the "Device" section:
Driver "radeon"
Option "TVDACLoadDetect" "TRUE"
Option "TVStandard" "ntsc"
Option "monitor-S-video" "TV-monitor"
In the "Monitor" Section:
Option "PreferredMode" "800x600"
In the "Screen" section:
DefaultDepth 24
SubSection "Display"
Depth 24
Modes "800x600"
EndSubSection