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In Lubuntu we have folder /home/username/.config/autostart. Its OK, but how I can autostart app on my "invisible" desktop and in fullscreen (like after pressing F11)?

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You Want to look into a program called devilspie. Ubuntu-Link

It is in the repos so a simple sudo apt-get install devilspie will do it.

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+1 devilspie looks neat – Ash May 3 '13 at 23:59

According to the desktop entry spec, there don't appear to be any position-based properties in the standard entry keys.

If the specific application you're running accepts positional parameters though, you might be able to get it to work that way in the Exec entry.

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