I know I'm being a Johnny-come-lately to this question but I'd like to see if I can shed some light on this for anyone searching.
First, @ppetraki's answer is excellent.
The short answer to "Can I RAID SSDs and boot from them" is "Yes!". Here are instructions for 14.04. Instructions for RAID configuration on 12.04.x are identical, but this tutorial using 9.10 has pictures. Following here are some important gotchas and details I had to discover the hard way, through personal experience:
I'm running Ubuntu 12.04.5 with the 3.8 kernel on an MD RAID0 configuration and the SSD-friendly Btrfs filesystem. I run fstrim as a weekly cron.
My extra Btrfs mount options from fstab:
The 3.8 kernel is required if you want to use "compress=no" as a Btrfs mount option and may also be required for use of "fstrim", the manual trim command used for scheduled trim.
You must also manually align partitions (on any multi-partition setup, raid or not) on the SSDs BEFORE booting to the installer because depending on the page size of your SSD, only the first partition will be properly aligned (it took me a while to catch it) and this can severely impact drive lifespan. You can do this from a command prompt within the installer or from a live usb/disc before you attempt installation. Caveat: Do the math yourself. Fdisk will lie about alignment.
Further reading: I think Btrfs can even create its own raid arrays.
It's arguably unnecessary thanks to overprovisioning
14.04 is the first release to enable TRIM support out-of-the-box but it's trivial to enable on previous distributions, provided you are using kernel 2.6.33+.
Depending on your chosen filesystem, you can enable trim/discard by editing your fstab and setting the appropriate mount option. The difference between doing this and running it via cron is that the first will trim/discard on-the-fly and the second will do it in a lump on a schedule. I use the second.
Does it matter? Supposedly, the online discard (using the mount option) is not wonderfully implemented and is slow so it's "not recommended". I can tell you that my "hdd" (hehe) lights go nuts for 10-20 minutes when the weekly cron job runs but the OS responsiveness is almost completely unaffected.
Booting from the array: Though I don't see this in a quick scan of the ubuntu 14.04 instructions, I had to create an additional primary partition that is NOT part of my raid arrays. Disk 0 has a 500mb primary partition of ext3fs. During installation I told the installer this was to be mounted at "/boot" and I set the bootable flag. The bootloader is then installed here so the OS can start and then mount the RAID. The remaining Disk 0 space is divided between 2 partitions which are later used for the MD arrays that become "/" and "/swap". Disk 1 has the same, but no boot partition. Also, I only created the swap in case I need it sometime and btrfs does not support swapfiles. This partition is never mounted; after installation, I commented it out in my fstab.
Forgive all the edits, just trying to get it all out there.