Normally you add the script that starts a daemon into /etc/rcS.d/ (the S means at Startup) and the script should automatically be launched the next time you boot. (Generally you softlink scripts there from their original path.) This can also be done with the update-rc.d tool {requires root privileges}.
Sadly I'm not sure where exactly the crond starter script is, but it should be automatically configured for you to start up at boot, and before playing with system directories I would say that make a sanity check and see wht happens if you run crontab -e and add in a new line like this: */1 * * * * echo "Cron works", and you should get the string Cron works in a system mail (provided that you have postfix configured).
Also don't forget to remove the cronjob once it has been tested as it will send that string every minute to you and it quickly gets annoying.